Sūtra 8·4·14
उपसर्गाद् असमासे ऽपि णोपदेशस्य
upasargād asamāse 'pi ṇopadeśasya
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Of a root which has ṇa in its original enunciation, when it comes after a cause of such change standing in an upasarga, even though the word be not a samâsa, the na is changed into ṇa
Padapāṭha upasargāt asamāse api ṇaupadeśasyaउपसर्गात् असमासे अपि णौपदेशस्य