Sūtra 8·4·6
विभाषौषधिवनस्पतिभ्यः
vibhāṣauṣadhivanaspatibhyaḥ
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The na of vana is optionally replaced by ṇa, when the cause of change occurs in the first member of the compound and which denotes a perrenial herb or a forest tree.
Padapāṭha vibhāṣāoṣadhivanaspatibhyaḥविभाषाओषधिवनस्पतिभ्यः