Sūtra 4·2·6
द्वन्द्वाच् छः
dvandvāc chaḥ
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The affix cha comes after the Dvandva compound of the names of lunar mansions, when it is in the instrumental case in construction, to signify time connected with the asterism whether there be a specification or not.
Padapāṭha dvandvāt chaḥद्वन्द्वात् छः