Sūtra 7·3·23
दीर्घाच् च वरुणस्य
dīrghāc ca varuṇasya
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Before a Taddhita affix having an indicatory ñ, ṇ or ka, in a Dvandva compound of god-names, the vṛiddhi is not substituted for the first vowel of varuṇa when a long vowel precedes it.
Padapāṭha dīrghāt ca varuṇasyaदीर्घात् च वरुणस्य