Sūtra 5·3·112
पूगाञ् ञ्यो ऽग्रामणीपूर्वात्
pūgāñ ñyo 'grāmaṇīpūrvāt
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The affix ñya (±‘ya) is added without changing the connotation, to a word denoting a horde, but not when the word is derived from the name of their leader.
Padapāṭha pūgāt ñyaḥ agrāmaṇīpūrvātपूगात् ञ्यः अग्रामणीपूर्वात्