Sūtra 7·3·21
देवताद्वन्द्वे च
devatādvandve ca
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Before a Taddhita affix having an indicatory ñ, ṇ or k, the Vṛiddhi is substituted for the first vowels of both members a Dvanda compound of the names of Devas.
Padapāṭha devatādvandve caदेवताद्वन्द्वे च