Sūtra 8·2·108
तयोर् य्वाव् अचि संहितायाम्
tayor yvāv aci saṃhitāyām
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For these vowels i and u are substituted y and v when a vowel follows them in a samhita (in an unbroken flow of speech).
Padapāṭha tayoḥ yvau aci saṃhitāyāmतयोः य्वौ अचि संहितायाम्