Sūtra 2·3·25
विभाषा गुणे ऽस्त्रियाम्
vibhāṣā guṇe 'striyām
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The fifth case-affix is employed optionally when the noun expresses an attribute, being the causa of an action, and not being of the feminine gender.
Padapāṭha vibhāṣā guṇe astriyāmविभाषा गुणे अस्त्रियाम्