Sūtra 3·2·180
विप्रसम्भ्यो ड्व् असञ्ज्ञायाम्
viprasambhyo ḍv asañjñāyām
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The affix ḍu comes after the verb bhū when it is preceded by the upasargas vi, pra and sam provided that the word to be formed does not mean an appellative.
Padapāṭha viprasambhyaḥ ḍu asañjñāyāmविप्रसम्भ्यः डु असञ्ज्ञायाम्