Sūtra 5·1·20
असमासे निष्कादिभ्यः
asamāse niṣkādibhyaḥ
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The affix ṭhak comes after the words niṣka &c, when they are not parts of a compound, the sense of the affix being that taught in the subsequent sûtras upto V.1.63.
Padapāṭha asamāse niṣkaādibhyaḥअसमासे निष्कआदिभ्यः