Sūtra 5·1·21
शताच् च ठन्यताव् अशते
śatāc ca ṭhanyatāv aśate
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The affixes ṭhan (—/—ika) and yat (—/ya) come in the senses taught upto V.1.63 after the word śata, when it is not a part of a compound, and when it does not mean merely a ‘hundred’.
Padapāṭha śatāt ca ṭhanyatau aśateशतात् च ठन्यतौ अशते