Sūtra 5·4·104
ब्रह्मणो जानपदाख्यायाम्
brahmaṇo jānapadākhyāyām
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The affix ṭach comes after the word brahnnma in a Tatpurusha compound, when the compound denotes a person belonging to a certain country..
Padapāṭha brahmaṇaḥ jānapadaākhyāyāmब्रह्मणः जानपदआख्यायाम्