Sūtra 5·4·61
सपत्रनिष्पत्राद् अतिव्यथने
sapatraniṣpatrād ativyathane
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The affix ḍâch comes after the words sapatra, and nishpatra followed by the verb kṛi, when the sense is that of causing intense pain.
Padapāṭha sapatraniṣpatrāt ativyathaneसपत्रनिष्पत्रात् अतिव्यथने