Sūtra 5·4·36
तद्युक्तात् कर्मणो ऽण्
tadyuktāt karmaṇo 'ṇ
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The affix aṇ comes after the word karman ‘occupation’, when it occurs in connection therewith (i. e. when it is the result of an oral message or commission).
Padapāṭha tadyuktāt karmaṇaḥ aṇतद्युक्तात् कर्मणः अण्