Sūtra 5·4·71
नञस् तत्पुरुषात्
nañas tatpuruṣāt
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The samâsânta affix does not come after a Tatpurusha compound of words like râjan &c, herein taught, when the negative particle na precedes them.
Padapāṭha nañaḥ tatpuruṣātनञः तत्पुरुषात्