Sūtra 3·1·72
संयसश् च
saṃyasaś ca
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The affix śyan is optionally employed after the root yas ‘to strive’, when it is preceded by the preposition sam, and when a sârvadhâtuka affix denoting an agent, follows.
Padapāṭha saṃyasaḥ caसंयसः च