Sūtra 4·3·154
प्राणिरजतादिभ्यो ऽञ्
prāṇirajatādibhyo 'ñ
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The affix añ comes in the sense of ‘its product or part’, after words expressing living beings, and after rajata &c.
Padapāṭha prāṇirajataādibhyaḥ añप्राणिरजतआदिभ्यः अञ्