Sūtra 6·2·123
तत्पुरुषे शालायां नपुंसके
tatpuruṣe śālāyāṃ napuṃsake
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The word śālā at the end of a Tatpurusha compound when exhibited in the Neuter has acute on the first syllable.
Padapāṭha tatpuruṣe śālāyām napuṃsakeतत्पुरुषे शालायाम् नपुंसके