Sūtra 6·2·14
मात्रोपज्ञोपक्रमच्छाये नपुंसके
mātropajñopakramacchāye napuṃsake
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The first member of a Tatpurusha preserves its accent before the words mātrā, upajñā, upakrama and chāyā when these words appear as neuter.
Padapāṭha mātrāupajñāupakramachāye napuṃsakeमात्राउपज्ञाउपक्रमछाये नपुंसके