Sūtra 6·2·128
पललसूपशाकं मिश्रे
palalasūpaśākaṃ miśre
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In a Tatpurusha ending in palala, sūpa and śāka the acute falls on the first syllable of these, when the compound denotes a food mixed or seasoned with something.
Padapāṭha palalasūpaśākam miśreपललसूपशाकम् मिश्रे