Sūtra 6·2·76
शिल्पिनि च अकृञः
śilpini ca akṛñaḥ
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And when such a compound ending in aṇ affix denotes the name of a professional man, but not when the second term is kāra (derived from kṛñ) the acute is on the first syllable of the first word.
Padapāṭha śilpini ca akṛñaḥशिल्पिनि च अकृञः