Sūtra 6·2·112
कर्णो वर्णलक्षणात्
karṇo varṇalakṣaṇāt
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In a Bahuvrûhi compound, the word karṇa standing as second member, has acute on the first syllable, when it is preceded by a word denoting color or mark.
Padapāṭha karṇaḥ varṇalakṣaṇātकर्णः वर्णलक्षणात्