Sūtra 6·1·64
धात्वादेः षः सः
dhātvādeḥ ṣaḥ saḥ
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There is the substitution of s in the room of the ṣ being the initial of a verbal root as enunciated in the Dhâtupâtha.
German Für das im grammatischen Unterrichtssystem im Anlaut einer Wurzel stehende ṣ wird s substituirt. (64)
Padapāṭha dhātuādeḥ ṣaḥ saḥधातुआदेः षः सः